Synthesis and electroluminescent properties of highly efficient anthracene derivatives with bulky side groups
Identifieur interne : 000D09 ( Chine/Analysis ); précédent : 000D08; suivant : 000D10Synthesis and electroluminescent properties of highly efficient anthracene derivatives with bulky side groups
Auteurs : RBID : Pascal:09-0356996Descripteurs français
- Pascal (Inist)
- Composé organique, Dispositif électroluminescent, Aluminium, Evaluation performance, Chromaticité, Rendement quantique, Luminance, Luminescence, Diode électroluminescente organique, Lumière bleue, Dérivé de l'anthracène, Oxyde d'indium, Oxyde d'étain, Amine aromatique polycyclique, Anthracène, Quinoléin-8-ol, Complexe d'aluminium, Fluorure de lithium, Dispositif optoélectronique, Electronique organique, ITO, LiF.
- Wicri :
- concept : Aluminium.
English descriptors
- KwdEn :
- Aluminium, Aluminium complex, Anthracene, Anthracene derivatives, Blue light, Chromaticity, Electroluminescent device, Indium oxide, Lithium fluoride, Luminance, Luminescence, Optoelectronic device, Organic compounds, Organic electronics, Organic light emitting diodes, Performance evaluation, Polycyclic aromatic amines, Quantum yield, Tin oxide.
Abstract
Three new asymmetric light emitting organic compounds were synthesized with diphenylamine or triphenylamine side groups; 10-(3,5-diphenylphenyl)-N,N-diphenylanthracen-9-amine (MADa), 4-(10-(3,5-diphenylphenyl)anthracen-9-yl)-N,N-diphenylaniline (MATa), and 4-(10-(3',5'-diphenylbiphenyl-4-yl)anthracen-9-yl)-N,N-diphenylaniline (TATa). MATa and TATa had a PLmax at 463 nm in the blue region, and MADa had a PLmax at 498 nm. MADa and MATa had Tg values greater than 120 °C, and TATa had a Tg of 139 °C. EL devices containing the synthesized compounds were fabricated in the configuration: ITO/4,4', 4"-tris(N-(2-naphthyl)-N-phenyl-amino)-triphenylamine (2-TNATA) (60 nm)/N,N'-bis(naphthalen-1-yl)-N,N'-bis(phenyl)benzidine (NPB) (15 nm)/MADa or MATa or TATa or 9,1 0-di(2'-naphthyl)anthracene (MADN) (30 nm)/8-hydroxyquinoline aluminum (Alq3) (30 nm)/LiF (1 nm)/Al (200 nm). The efficiency and color coordinate values (respectively) were 10.3 cd/A and (0.199, 0.152: bluish-green) for the MADa device, 4.67 cd/A and (0.151, 0.177) for the MATa device, and 6.07 cd/A and (0.149, 0.177) for the TATa device. The TATa device had a high external quantum efficiency (EQE) of 6.19%, and its luminance and power efficiencies and life-time were more than twice those of the MADN device.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Synthesis and electroluminescent properties of highly efficient anthracene derivatives with bulky side groups</title><author><name sortKey="Kim, Soo Kang" uniqKey="Kim S">Soo-Kang Kim</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry/Display Research Center, The Catholic University of Korea</s1><s2>Bucheon, Kyunggi 420-743</s2><s3>KOR</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>Corée du Sud</country><wicri:noRegion>Bucheon, Kyunggi 420-743</wicri:noRegion></affiliation></author><author><name>BING YANG</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>State Key Laboratory of Supramolecular Structure and Materials, Jilin University</s1><s2>Changchun 130012</s2><s3>CHN</s3><sZ>2 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>République populaire de Chine</country><placeName><settlement type="city">Changchun</settlement><region type="province">Jilin</region><region type="groupement">Dongbei</region></placeName></affiliation></author><author><name sortKey="Park, Young Il" uniqKey="Park Y">Young-Il Park</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry/Display Research Center, The Catholic University of Korea</s1><s2>Bucheon, Kyunggi 420-743</s2><s3>KOR</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>Corée du Sud</country><wicri:noRegion>Bucheon, Kyunggi 420-743</wicri:noRegion></affiliation></author><author><name>YUGUANG MA</name><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>State Key Laboratory of Supramolecular Structure and Materials, Jilin University</s1><s2>Changchun 130012</s2><s3>CHN</s3><sZ>2 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>République populaire de Chine</country><placeName><settlement type="city">Changchun</settlement><region type="province">Jilin</region><region type="groupement">Dongbei</region></placeName></affiliation></author><author><name sortKey="Lee, Jun Yeob" uniqKey="Lee J">Jun-Yeob Lee</name><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Department of Polymer Engineering, Dankook University</s1><s2>Yongin, Kyung-gi 448-701</s2><s3>KOR</s3><sZ>5 aut.</sZ></inist:fA14><country>Corée du Sud</country><wicri:noRegion>Yongin, Kyung-gi 448-701</wicri:noRegion></affiliation></author><author><name sortKey="Kim, Hyoung Juhn" uniqKey="Kim H">Hyoung-Juhn Kim</name><affiliation wicri:level="1"><inist:fA14 i1="04"><s1>Center for Fuel Cell Research, Korea Institute of Science and Technology</s1><s2>Hawolgok, Seoul 136-791</s2><s3>KOR</s3><sZ>6 aut.</sZ></inist:fA14><country>Corée du Sud</country><wicri:noRegion>Hawolgok, Seoul 136-791</wicri:noRegion></affiliation></author><author><name sortKey="Park, Jongwook" uniqKey="Park J">Jongwook Park</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry/Display Research Center, The Catholic University of Korea</s1><s2>Bucheon, Kyunggi 420-743</s2><s3>KOR</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>Corée du Sud</country><wicri:noRegion>Bucheon, Kyunggi 420-743</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">09-0356996</idno><date when="2009">2009</date><idno type="stanalyst">PASCAL 09-0356996 INIST</idno><idno type="RBID">Pascal:09-0356996</idno><idno type="wicri:Area/Main/Corpus">005186</idno><idno type="wicri:Area/Main/Repository">004A49</idno><idno type="wicri:Area/Chine/Extraction">000D09</idno></publicationStmt><seriesStmt><idno type="ISSN">1566-1199</idno><title level="j" type="abbreviated">Org. electron.</title><title level="j" type="main">Organic electronics </title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Aluminium</term><term>Aluminium complex</term><term>Anthracene</term><term>Anthracene derivatives</term><term>Blue light</term><term>Chromaticity</term><term>Electroluminescent device</term><term>Indium oxide</term><term>Lithium fluoride</term><term>Luminance</term><term>Luminescence</term><term>Optoelectronic device</term><term>Organic compounds</term><term>Organic electronics</term><term>Organic light emitting diodes</term><term>Performance evaluation</term><term>Polycyclic aromatic amines</term><term>Quantum yield</term><term>Tin oxide</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Composé organique</term><term>Dispositif électroluminescent</term><term>Aluminium</term><term>Evaluation performance</term><term>Chromaticité</term><term>Rendement quantique</term><term>Luminance</term><term>Luminescence</term><term>Diode électroluminescente organique</term><term>Lumière bleue</term><term>Dérivé de l'anthracène</term><term>Oxyde d'indium</term><term>Oxyde d'étain</term><term>Amine aromatique polycyclique</term><term>Anthracène</term><term>Quinoléin-8-ol</term><term>Complexe d'aluminium</term><term>Fluorure de lithium</term><term>Dispositif optoélectronique</term><term>Electronique organique</term><term>ITO</term><term>LiF</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Aluminium</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Three new asymmetric light emitting organic compounds were synthesized with diphenylamine or triphenylamine side groups; 10-(3,5-diphenylphenyl)-N,N-diphenylanthracen-9-amine (MADa), 4-(10-(3,5-diphenylphenyl)anthracen-9-yl)-N,N-diphenylaniline (MATa), and 4-(10-(3',5'-diphenylbiphenyl-4-yl)anthracen-9-yl)-N,N-diphenylaniline (TATa). MATa and TATa had a PL<sub>max</sub> at 463 nm in the blue region, and MADa had a PL<sub>max</sub> at 498 nm. MADa and MATa had T<sub>g</sub> values greater than 120 °C, and TATa had a T<sub>g</sub> of 139 °C. EL devices containing the synthesized compounds were fabricated in the configuration: ITO/4,4', 4"-tris(N-(2-naphthyl)-N-phenyl-amino)-triphenylamine (2-TNATA) (60 nm)/N,N'-bis(naphthalen-1-yl)-N,N'-bis(phenyl)benzidine (NPB) (15 nm)/MADa or MATa or TATa or 9,1 0-di(2'-naphthyl)anthracene (MADN) (30 nm)/8-hydroxyquinoline aluminum (Alq<sub>3</sub>) (30 nm)/LiF (1 nm)/Al (200 nm). The efficiency and color coordinate values (respectively) were 10.3 cd/A and (0.199, 0.152: bluish-green) for the MADa device, 4.67 cd/A and (0.151, 0.177) for the MATa device, and 6.07 cd/A and (0.149, 0.177) for the TATa device. The TATa device had a high external quantum efficiency (EQE) of 6.19%, and its luminance and power efficiencies and life-time were more than twice those of the MADN device.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1566-1199</s0></fA01><fA03 i2="1"><s0>Org. electron.</s0></fA03><fA05><s2>10</s2></fA05><fA06><s2>5</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Synthesis and electroluminescent properties of highly efficient anthracene derivatives with bulky side groups</s1></fA08><fA11 i1="01" i2="1"><s1>KIM (Soo-Kang)</s1></fA11><fA11 i1="02" i2="1"><s1>BING YANG</s1></fA11><fA11 i1="03" i2="1"><s1>PARK (Young-Il)</s1></fA11><fA11 i1="04" i2="1"><s1>YUGUANG MA</s1></fA11><fA11 i1="05" i2="1"><s1>LEE (Jun-Yeob)</s1></fA11><fA11 i1="06" i2="1"><s1>KIM (Hyoung-Juhn)</s1></fA11><fA11 i1="07" i2="1"><s1>PARK (Jongwook)</s1></fA11><fA14 i1="01"><s1>Department of Chemistry/Display Research Center, The Catholic University of Korea</s1><s2>Bucheon, Kyunggi 420-743</s2><s3>KOR</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ><sZ>7 aut.</sZ></fA14><fA14 i1="02"><s1>State Key Laboratory of Supramolecular Structure and Materials, Jilin University</s1><s2>Changchun 130012</s2><s3>CHN</s3><sZ>2 aut.</sZ><sZ>4 aut.</sZ></fA14><fA14 i1="03"><s1>Department of Polymer Engineering, Dankook University</s1><s2>Yongin, Kyung-gi 448-701</s2><s3>KOR</s3><sZ>5 aut.</sZ></fA14><fA14 i1="04"><s1>Center for Fuel Cell Research, Korea Institute of Science and Technology</s1><s2>Hawolgok, Seoul 136-791</s2><s3>KOR</s3><sZ>6 aut.</sZ></fA14><fA20><s1>822-833</s1></fA20><fA21><s1>2009</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>27255</s2><s5>354000187505060130</s5></fA43><fA44><s0>0000</s0><s1>© 2009 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>35 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>09-0356996</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Organic electronics </s0></fA64><fA66 i1="01"><s0>NLD</s0></fA66><fC01 i1="01" l="ENG"><s0>Three new asymmetric light emitting organic compounds were synthesized with diphenylamine or triphenylamine side groups; 10-(3,5-diphenylphenyl)-N,N-diphenylanthracen-9-amine (MADa), 4-(10-(3,5-diphenylphenyl)anthracen-9-yl)-N,N-diphenylaniline (MATa), and 4-(10-(3',5'-diphenylbiphenyl-4-yl)anthracen-9-yl)-N,N-diphenylaniline (TATa). MATa and TATa had a PL<sub>max</sub> at 463 nm in the blue region, and MADa had a PL<sub>max</sub> at 498 nm. MADa and MATa had T<sub>g</sub> values greater than 120 °C, and TATa had a T<sub>g</sub> of 139 °C. EL devices containing the synthesized compounds were fabricated in the configuration: ITO/4,4', 4"-tris(N-(2-naphthyl)-N-phenyl-amino)-triphenylamine (2-TNATA) (60 nm)/N,N'-bis(naphthalen-1-yl)-N,N'-bis(phenyl)benzidine (NPB) (15 nm)/MADa or MATa or TATa or 9,1 0-di(2'-naphthyl)anthracene (MADN) (30 nm)/8-hydroxyquinoline aluminum (Alq<sub>3</sub>) (30 nm)/LiF (1 nm)/Al (200 nm). The efficiency and color coordinate values (respectively) were 10.3 cd/A and (0.199, 0.152: bluish-green) for the MADa device, 4.67 cd/A and (0.151, 0.177) for the MATa device, and 6.07 cd/A and (0.149, 0.177) for the TATa device. The TATa device had a high external quantum efficiency (EQE) of 6.19%, and its luminance and power efficiencies and life-time were more than twice those of the MADN device.</s0></fC01><fC02 i1="01" i2="X"><s0>001D03F15</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Composé organique</s0><s2>NA</s2><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Organic compounds</s0><s2>NA</s2><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Compuesto orgánico</s0><s2>NA</s2><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Dispositif électroluminescent</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Electroluminescent device</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Dispositivo electroluminiscente</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Aluminium</s0><s2>NC</s2><s2>FR</s2><s2>FX</s2><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Aluminium</s0><s2>NC</s2><s2>FR</s2><s2>FX</s2><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Aluminio</s0><s2>NC</s2><s2>FR</s2><s2>FX</s2><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Evaluation performance</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Performance evaluation</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="SPA"><s0>Evaluación prestación</s0><s5>04</s5></fC03><fC03 i1="05" i2="X" l="FRE"><s0>Chromaticité</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="ENG"><s0>Chromaticity</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="SPA"><s0>Cromaticidad</s0><s5>05</s5></fC03><fC03 i1="06" i2="X" l="FRE"><s0>Rendement quantique</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="ENG"><s0>Quantum yield</s0><s5>06</s5></fC03><fC03 i1="06" i2="X" l="SPA"><s0>Rendimiento quántico</s0><s5>06</s5></fC03><fC03 i1="07" i2="X" l="FRE"><s0>Luminance</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="ENG"><s0>Luminance</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="SPA"><s0>Luminancia</s0><s5>07</s5></fC03><fC03 i1="08" i2="X" l="FRE"><s0>Luminescence</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="ENG"><s0>Luminescence</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="SPA"><s0>Luminiscencia</s0><s5>08</s5></fC03><fC03 i1="09" i2="3" l="FRE"><s0>Diode électroluminescente organique</s0><s5>09</s5></fC03><fC03 i1="09" i2="3" l="ENG"><s0>Organic light emitting diodes</s0><s5>09</s5></fC03><fC03 i1="10" i2="X" l="FRE"><s0>Lumière bleue</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="ENG"><s0>Blue light</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="SPA"><s0>Luz azul</s0><s5>10</s5></fC03><fC03 i1="11" i2="X" l="FRE"><s0>Dérivé de l'anthracène</s0><s5>22</s5></fC03><fC03 i1="11" i2="X" l="ENG"><s0>Anthracene derivatives</s0><s5>22</s5></fC03><fC03 i1="11" i2="X" l="SPA"><s0>Antraceno derivado</s0><s5>22</s5></fC03><fC03 i1="12" i2="X" l="FRE"><s0>Oxyde d'indium</s0><s5>23</s5></fC03><fC03 i1="12" i2="X" l="ENG"><s0>Indium oxide</s0><s5>23</s5></fC03><fC03 i1="12" i2="X" l="SPA"><s0>Indio óxido</s0><s5>23</s5></fC03><fC03 i1="13" i2="X" l="FRE"><s0>Oxyde d'étain</s0><s5>24</s5></fC03><fC03 i1="13" i2="X" l="ENG"><s0>Tin oxide</s0><s5>24</s5></fC03><fC03 i1="13" i2="X" l="SPA"><s0>Estaño óxido</s0><s5>24</s5></fC03><fC03 i1="14" i2="3" l="FRE"><s0>Amine aromatique polycyclique</s0><s5>25</s5></fC03><fC03 i1="14" i2="3" l="ENG"><s0>Polycyclic aromatic amines</s0><s5>25</s5></fC03><fC03 i1="15" i2="X" l="FRE"><s0>Anthracène</s0><s2>NK</s2><s2>FX</s2><s5>26</s5></fC03><fC03 i1="15" i2="X" l="ENG"><s0>Anthracene</s0><s2>NK</s2><s2>FX</s2><s5>26</s5></fC03><fC03 i1="15" i2="X" l="SPA"><s0>Antraceno</s0><s2>NK</s2><s2>FX</s2><s5>26</s5></fC03><fC03 i1="16" i2="X" l="FRE"><s0>Quinoléin-8-ol</s0><s2>NK</s2><s2>FR</s2><s2>FF</s2><s5>27</s5></fC03><fC03 i1="17" i2="X" l="FRE"><s0>Complexe d'aluminium</s0><s5>28</s5></fC03><fC03 i1="17" i2="X" l="ENG"><s0>Aluminium complex</s0><s5>28</s5></fC03><fC03 i1="17" i2="X" l="SPA"><s0>Aluminio complejo</s0><s5>28</s5></fC03><fC03 i1="18" i2="X" l="FRE"><s0>Fluorure de lithium</s0><s5>29</s5></fC03><fC03 i1="18" i2="X" l="ENG"><s0>Lithium fluoride</s0><s5>29</s5></fC03><fC03 i1="18" i2="X" l="SPA"><s0>Litio fluoruro</s0><s5>29</s5></fC03><fC03 i1="19" i2="X" l="FRE"><s0>Dispositif optoélectronique</s0><s5>31</s5></fC03><fC03 i1="19" i2="X" l="ENG"><s0>Optoelectronic device</s0><s5>31</s5></fC03><fC03 i1="19" i2="X" l="SPA"><s0>Dispositivo optoelectrónico</s0><s5>31</s5></fC03><fC03 i1="20" i2="X" l="FRE"><s0>Electronique organique</s0><s5>32</s5></fC03><fC03 i1="20" i2="X" l="ENG"><s0>Organic electronics</s0><s5>32</s5></fC03><fC03 i1="20" i2="X" l="SPA"><s0>Electrónica orgánica</s0><s5>32</s5></fC03><fC03 i1="21" i2="X" l="FRE"><s0>ITO</s0><s4>INC</s4><s5>82</s5></fC03><fC03 i1="22" i2="X" l="FRE"><s0>LiF</s0><s4>INC</s4><s5>83</s5></fC03><fN21><s1>257</s1></fN21><fN44 i1="01"><s1>OTO</s1></fN44><fN82><s1>OTO</s1></fN82></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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